Zeolitic imidazolate framework-L loaded on melamine foam for removal tetracycline hydrochloride from water

Zeolitic imidazolate framework-L/melamine foam (ZIF-L/MF) is fabricated by an in situ growth method to treat the tetracycline hydrochloride in wastewater. The results show that a large amount of leaf-like ZIF-L is vertically grown on the MF surface. ZIF-L/MF exhibits well adsorption performance with a maximum adsorption ability of 1346 mg/g. The pseudo-second-order kinetic model and the Langmuir isotherm model are used to describe the adsorption process well. In addition, the influences of pH and coexisting ions are studied. According to the experimental data and analysis, the adsorption mechanisms may involve H-bonding, π–π interaction, and weak electrostatic interaction. A dynamic adsorption experiment is also performed, and the results show that the time required to achieve the same removal efficiency as static adsorption is reduced by half. This work shows that the obtained ZIF-L/MF has practical applications in antibiotic adsorption.