On the mechanism of autocatalytic thermal decomposition of some secondary nitramines

被引：0

作者：

R. S. Stepanov

L. A. Kruglyakova

机构：

[1] Siberian State Technological University,

来源：

Russian Journal of General Chemistry | 2017年 / 87卷

关键词：

thermal decomposition; secondary nitramines; nucleophilic agent; acid-base solvent; acrylic acid; methyleneimine;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Mechanism of autocatalytic action of picric acid during thermal decomposition of N,2,4,6-tetranitro-Nmethylaniline has been studied for the first time. The process occurs as nucleophilic substitution of N,2,4,6-tetranitroanilinium ion with picrate one to form N,2,4,6-tetranitroaniline and trinitroanisole. In contrast to the case of aromatic nitramines, thermal decomposition of secondary alkylnitramines is accompanied by acid-base catalysis.

引用

页码：204 / 207

页数：3