On the mechanism of autocatalytic thermal decomposition of some secondary nitramines

被引：0

作者：

R. S. Stepanov

L. A. Kruglyakova

机构：

[1] Siberian State Technological University,

来源：

Russian Journal of General Chemistry | 2017年 / 87卷

关键词：

thermal decomposition; secondary nitramines; nucleophilic agent; acid-base solvent; acrylic acid; methyleneimine;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Mechanism of autocatalytic action of picric acid during thermal decomposition of N,2,4,6-tetranitro-Nmethylaniline has been studied for the first time. The process occurs as nucleophilic substitution of N,2,4,6-tetranitroanilinium ion with picrate one to form N,2,4,6-tetranitroaniline and trinitroanisole. In contrast to the case of aromatic nitramines, thermal decomposition of secondary alkylnitramines is accompanied by acid-base catalysis.

引用

页码：204 / 207

页数：3

共 14 条

[1]

Farmer R.C.(1920)undefined J. Chem. Soc. 117 1603-undefined

[2]

Hinshelwood C.N.(1921)undefined J. Chem. Soc. 119–120 721-undefined

[3]

Robertson A.I.B.(1948)undefined Trans. Faraday Soc. 44 677-undefined

[4]

Cook M.A.(1956)undefined Ind. Eng. Chem. 48 1090-undefined

[5]

Abegg M.T.(1961)undefined Zh. Fiz. Khim. 35 521-undefined

[6]

Dubovitskii F.I.(2008)undefined Izv. Vuzov, Ser. Khim. Khim. Tekhnol. 51 31-undefined

[7]

Manelis G.B.(1998)undefined Izv. Vuzov, Ser. Khim. Khim. Tekhnol. 41 35-undefined

[8]

Smirnov L.P.(undefined)undefined undefined undefined undefined-undefined

[9]

Kruglyakova L.A.(undefined)undefined undefined undefined undefined-undefined

[10]

Stepanov R.S.(undefined)undefined undefined undefined undefined-undefined

← 1 2 →