Synthesis, Structure and Properties of an Organically Templated Molybdate Zn2(bpe)Mo2O8 (bpe = 1,2-Bis(4-pyridyl)ethane)

被引：0
作者：
Wen-Ju Wang
Zhe-Yu Zhang
Ze-Min Mei
Feng-Yan Li
机构：
[1] Baicheng Teacher’s College,Department of Chemistry
[2] Northeast Normal University,Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry
来源：
Journal of Cluster Science | 2016年 / 27卷
关键词：
Metal-oxide organic framework; Molybdenum oxides; Crystal structure;
D O I：
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中图分类号：
学科分类号：
摘要：
A new organically templated molybdenum oxides compound Zn2(bpe)Mo2O8 (bpe = 1,2-bis(4-pyridyl)ethane) has been hydrothermal synthesized and characterized by single X-ray analysis, element analysis, IR spectroscopy, TG analysis, diffuse reflectance UV–Vis spectra. Compound 1 shows a three-dimensional net-like structure, where the bimetallic oxide layers {ZnMoO4} were knitted together with the bpe ligands. The optical band gap for 1 was 2.5 eV, which is comparable to that of TiO2. Moreover, the photoluminescent properties of 1 have been investigated at room temperature.
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页码：617 / 624
页数：7
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