Thermodynamics of the vaporization of alkyl compounds of zinc, selenium, cadmium, tellurium, and their equimolecular solutions

被引：0

作者：

S. I. Gerasimchuk

Yu. P. Pavlovskii

I. B. Sobechko

Yu. Ya. Van-Chin-Syan

机构：

[1] Lviv Polytechnical National University,

来源：

Russian Journal of Physical Chemistry A | 2014年 / 88卷

关键词：

diethylzinc; diethylselenium; dimethylcadmium; dimethyltellurium; solution; vapor pressure; enthalpies of vaporization;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Enthalpies of vaporization for diethylzinc, diethylselenium, dimethylcadmium, and dimethyltellurium, and their equimolecular solutions are determined via calorimetry and tensiometry. It is found that in the liquid phase and the temperature range of 273-368 K, equimolecular solutions of ZnEt2 · SeEt2 behave as single-component systems that dissociate into constituting substances upon vaporization. At the same time, equimolecular solutions of ZnEt2 · SeMe2, CdMe2 · SeMe2, and CdMe2 · TeMe2 consist of two components whether in a liquid or vapor phase.

引用

页码：365 / 371

页数：6

共 41 条

[1] Thermodynamics of the vaporization of alkyl compounds of zinc, selenium, cadmium, tellurium, and their equimolecular solutions
Gerasimchuk, S. I.
Pavlovskii, Yu. P.
Sobechko, I. B.
Van-Chin-Syan, Yu. Ya.
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2014, 88 (03) : 365 - 371
[2] Thermodynamics of Formation and Vaporization of Tin–Zinc Solutions
S. A. Trebukhov
V. N. Volodin
O. V. Ulanova
A. V. Nitsenko
N. M. Burabaeva
Russian Journal of Inorganic Chemistry, 2021, 66 : 1722 - 1729
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Burabaeva, N. M.
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2021, 66 (11) : 1722 - 1729
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