Solubility of KF in four organic solvents and thermodynamic dissolution functions

被引:0
作者
Hua Li
Xiaoshuang Chen
机构
[1] Zhengzhou University,School of Chemical and Energy Engineering
[2] Xi’an Jiaotong University,School of Energy and Power Engineering
来源
Russian Journal of Physical Chemistry A | 2014年 / 88卷
关键词
solubilities; kKF; kpolar solvents; kcorrelation;
D O I
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中图分类号
学科分类号
摘要
The solubilities of potassium fluoride (KF) in protic and aprotic polar solvents (N,N-dimethylethanolamine, diethanolamine, pyridine, and sulfolane) were measured at temperatures ranging from 308.73 to 367.37 K, and the data were correlated using the modified Apelblat equation. The dissolution enthalpy and dissolution entropy were calculated from the solubility data. The interactions between solute and solvent were discussed. The data obtained can be helpful in the search of optimal ways of preparation of 2,3,4,5-tetrafluorobenzoic acid.
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页码:1265 / 1268
页数:3
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