Crystal structure of the low-temperature forms of cesium and rubidium orthophosphates

被引：0

作者：

V. I. Voronin

I. F. Berger

N. V. Proskurnina

D. V. Sheptyakov

B. N. Goshchitskii

E. I. Burmakin

S. S. Stroev

G. Sh. Shekhtman

机构：

[1] Russian Academy of Sciences,Institute of Metal Physics, Ural Division

[2] Russian Academy of Sciences,Institute of Solid

[3] ETH Zurich & Paul Scherrer Institute,State Chemistry, Ural Division

[4] Russian Academy of Sciences,Laboratory for Neutron Scattering

来源：

Inorganic Materials | 2008年 / 44卷

关键词：

Cesium; Bond Distance; Rubidium; Neutron Diffraction Pattern; Ammonium Dihydrogen;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The crystal structure of the low-temperature forms of the Cs3PO4 and Rb3PO4 orthophosphates has been determined for the first time by neutron diffraction using the Rietveld method. Cs3PO4 and Rb3PO4 are shown to be isostructural with K3PO4: orthorhombic cell (sp. gr. Pnma, Z = 4); lattice parameters a = 1.23177(6) nm, b = 0.88948(4) nm, c = 0.64197(3) nm for Cs3PO4; a = 1.17362(2) nm, b = 0.81046(1) nm, c = 0.615167(9) nm for Rb3PO4.

引用

页码：646 / 652

页数：6

共 50 条

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