Reactions of Alicyclic Epoxy Compounds with Nitrogen-Containing Nucleophiles

被引：0
|
作者：
L. I. Kas'yan
S. I. Okovityi
A. O. Kas'yan
机构：
[1] Dnepropetrovsk National University,Organisch
[2] per. Nauchnyi 13,chemische Laboratory
[3] Rheinisch-Westfalische technicshe Hochschule,undefined
来源：
Russian Journal of Organic Chemistry | 2004年 / 40卷
关键词：
Azide; Hydrazine; Reaction Path; Organic Product; Oxirane;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The review considers reactions of alicyclic epoxy compounds and their analogs with nitrogen-containing nucleophilic reagents, such as amines, azides, hydrazines, etc., biological aspects of these reactions, and properties of amino alcohols which are practically important organic products and synthons. Reaction mechanisms, including radical and radical ion reaction paths, the results of quantum-chemical studies, stereo- and regioselectivity aspects, and activation of epoxy substrates with achiral and chiral catalysts are discussed. The formation of nitrogen-containing heterocyclic systems via opening of the oxirane ring is described.
引用
收藏
页码：1 / 34
页数：33
相关论文
共 50 条
  • [21] THE REACTIONS OF CERTAIN NITROGEN-CONTAINING COMPOUNDS DERIVED FROM BENZOTRIFLUORIDE
    CARTWRIGHT, RA
    TATLOW, JC
    JOURNAL OF THE CHEMICAL SOCIETY, 1953, (JUL): : 1994 - 1998
  • [22] Unusual Behavior of Nitrogen-Containing Organosilicon Compounds in the Reactions with Isocyanates
    Belova, L. O.
    Golub, N. A.
    Storozhenko, P. A.
    Kirilin, A. D.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2021, 91 (05) : 820 - 827
  • [23] SYNTHESIS OF NITROGEN-CONTAINING HETEROCYCLES USING CONJUGATE ADDITION REACTIONS OF NUCLEOPHILES TO α,β-UNSATURATED IMINES
    Hachiya, Iwao
    Mizota, Isao
    Shimizu, Makoto
    HETEROCYCLES, 2012, 85 (05) : 993 - 1016
  • [24] Nitrogen-Containing Hydrochar: The Influence of Nitrogen-Containing Compounds on the Hydrochar Formation
    Alhnidi, Muhammad-Jamal
    Koerner, Paul
    Wuest, Dominik
    Pfersich, Jens
    Kruse, Andrea
    CHEMISTRYOPEN, 2020, 9 (08) : 864 - 873
  • [25] Nitrogen-containing carcinogenic compounds
    Joseph, L
    PROCEEDINGS OF THE SOCIETY FOR EXPERIMENTAL BIOLOGY AND MEDICINE, 1939, 41 (02): : 334 - 336
  • [26] REACTIONS OF NITROGEN-CONTAINING HETEROCYCLIC-COMPOUNDS WITH HEXAFLUOROBUTYNE-2
    DAVIDSON, JL
    MURRAY, IEP
    PRESTON, PN
    JOURNAL OF CHEMICAL RESEARCH-S, 1981, (05): : 126 - 126
  • [27] Catalytic oxidative reactions of organic compounds by nitrogen-containing copper complexes
    Barooah, N
    Sharma, S
    Sarma, BC
    Baruah, JB
    APPLIED ORGANOMETALLIC CHEMISTRY, 2004, 18 (09) : 440 - 445
  • [28] Reactions between copolymers with ester units and certain nitrogen-containing compounds
    Shmurak, I.L.
    International Polymer Science and Technology, 2014, 41 (10) : 19 - 21
  • [29] ETHYNYLCARBOCATIONS .2. REACTIONS OF 4-ETHYNYLPYRYLIUM PERCHLORATES WITH ALCOHOLS AND NITROGEN-CONTAINING NUCLEOPHILES
    MURADYAN, LA
    ZOLOTOVSKOVA, GP
    KOBLIK, AV
    KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 1990, (03): : 299 - 306
  • [30] Aromatic diosmatricyclic nitrogen-containing compounds
    Esteruelas, Miguel A.
    Masamunt, Ana B.
    Olivan, Montserrat
    Onate, Enrique
    Valencia, Marta
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (35) : 11612 - +
12345