Transition Metal Substituted Polyoxotungstates in the Catalytic Oxidation of 1H-Indene and 1,2-Dihydronaphthalene with Hydrogen Peroxide

被引：0
作者：
Ana C. Estrada
Mário M. Q. Simões
Isabel C. M. S. Santos
M. Graça P. M. S. Neves
Artur M. S. Silva
José A. S. Cavaleiro
Ana M. V. Cavaleiro
机构：
[1] University of Aveiro,CICECO, Department of Chemistry
[2] University of Aveiro,QOPNA, Department of Chemistry
来源：
Catalysis Letters | 2009年 / 128卷
关键词：
1; -indene; 1,2-dihydronaphthalene; Polyoxometalates; Polyoxotungstates; Hydrogen peroxide; Oxidation;
D O I：
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摘要：
The oxidation of 1H-indene and 1,2-dihydronaphthalene with hydrogen peroxide in the presence of Mn(III) or Fe(III) substituted Keggin-type polyoxotungstates is described. The products obtained depend on the catalyst and reaction conditions. Ring cleavage was observed, affording dialdehydes under mild and environmentally friendly conditions. Other main products were the α-hydroxy-ketones. The resulting epoxides seem to be intermediates to other oxygenated products.
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页码：281 / 289
页数：8
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