119Sn Mössbauer characterization of self assembled organotin(IV) complexes with Schiff bases containing amino acetate skeletons

被引：0
|
作者：
Smita Basu
Archana Mizar
Tushar S. Basu Baul
Eleonora Rivarola
机构：
[1] North-Eastern Hill University,Department of Chemistry
[2] NEHU Permanent Campus,Dipartimento di Chimica Inorganica e Analitica “Stanislao Cannizzaro”
[3] Università di Palermo,undefined
来源：
Hyperfine Interactions | 2008年 / 185卷
关键词：
Organotin(IV) carboxylates; Schiff base; Sn Mössbauer spectroscopy;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Several organotin(IV) compounds, viz., diorganotin(IV) compounds of the types Ph2SnLH (monomer), nBu2SnLH·OH2 (monomer), [Me2SnLH·OH2]2 (centrosymmetric dimer), [nBu2SnLH]3 (cyclic trinuclear), [Ph2SnLH]n (polymer), {[nBu2Sn(LH)]2O}2 (centrosymmetric tetranuclear), dinuclear di-/tri-mixed organotin(IV) compounds Ph2SnLH·Ph3SnCl (monomer) and triorganotin(IV) compounds of the types [Bz3SnLH]2 (centrosymmetric dimer) and [Me3SnL1H]n (Polymer) (LH = Schiff base carboxylate) have been studied in the solid state at liquid nitrogen temperature using 119Sn Mössbauer spectroscopy. The tin coordination geometry of the compounds determined from crystallography was correlated with the 119Sn Mössbauer results.
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页码：95 / 102
页数：7
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