Separation of racemiccloso-3,3-(η3,2-norbornadienyl)rhodacarboranes into enantiomers by HPLC on chiral stationary phasesinto enantiomers by HPLC on chiral stationary phases

被引:0
|
作者
M. M. Il'in
T. V. Zinevich
I. V. Pisareva
I. T. Chizhevsky
V. A. Davankov
机构
[1] Russian Academy of Sciences,A. N. Nesmeyanov Institute of Organoelement Compounds
来源
Russian Chemical Bulletin | 2000年 / 49卷
关键词
-rhodacarboranes; high-performance liquid chromatography; enantiomers; chiroptical properties;
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中图分类号
学科分类号
摘要
Racemiccloso-rhodacarboranes,vis.closo-(η3,2-C7H3-2-CR21)-1-R2-2-R3-3,1,2-RhC2B9H9 (R1=R2=R3=H; R1=H, R2=R3=Me; R1=R2=R3=Me) and (closo-2,2-(η3,2-C7H7-2-CH2)-2,1,7-RhC2B9H11), were successfully separated into enantiomers by high-performance liquid chromatography (HPLC).
引用
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页码:759 / 760
页数:1
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