Preparation and electrochemical properties of La1.0Sr1.0FeO4+δ as cathode material for intermediate temperature solid oxide fuel cells

被引:0
作者
Jianhua Huang
Xiaoying Jiang
Xiaobo Li
Aiqin Liu
机构
[1] Henan Institute of Science and Technology,College of Chemistry and Chemical Engineering
来源
Journal of Electroceramics | 2009年 / 23卷
关键词
Solid oxide fuel cells; Cathode material; K; NiF; -type structure; Electrochemical properties;
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中图分类号
学科分类号
摘要
Cathodic material La1.0Sr1.0FeO4+δ for an intermediate temperature solid oxide fuel cell (IT-SOFC) was prepared via the glycine-nitrate process and characterized by X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM). XRD results showed that no reaction occurred between the La1.0Sr1.0FeO4+δ electrode and Sm0.2Ce0.8O1.9 (SDC) electrolyte at 1000 °C. SEM results showed that the electrode formed good contact with the SDC electrolyte after sintering at 1000 °C for 2 h. The electrochemical properties of La1.0Sr1.0FeO4+δ were measured using electrochemical impedance spectroscopy (EIS) and steady state polarization measurement. At 700 °C, the polarization resistance was about 3.90 Ωcm2, and the lowest polarization overpotential was 57 mV at a current density of 55 mA cm−2.
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页码:67 / 71
页数:4
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