Study on the thermodynamic properties of cholesterol

被引:0
作者
L. Peng
X. Jiangjun
M. Fangquan
L. Xi
Z. Chaocan
机构
[1] Wuhan University of Technology,School of Sciences
[2] Wuhan University of Technology,School of Material Science and Technology
来源
Journal of Thermal Analysis and Calorimetry | 2008年 / 93卷
关键词
bond enthalpy; calorimetry; cholesterol; enthalpy; recycle;
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中图分类号
学科分类号
摘要
The standard molar enthalpy of combustion of cholesterol was measured at constant volume. According to value of ΔrUmθ(−14358.4±20.65 kJ mol−1), ΔrHmθ(−14385.7 kJ mol−1) of combustion reaction and ΔfHmθ(2812.9 kJ mol−1) of cholesterol were obtained from the reaction equation. The enthalpy of combustion reaction of cholesterol was also estimated by the average bond enthalpies. By design of a thermo-chemical recycle, the enthalpy of combustion of cholesterol were calculated between 283.15∼373.15 K. Besides, molar enthalpy and entropy of fusion of cholesterol was obtained by DSC technique.
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页码:485 / 488
页数:3
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