Synthesis of Ferrocene-Based Hyperbranched Polyether and Its Catalytic Performance for Thermal Decomposition of Ammonium Perchlorate

被引:0
作者
Ruoli Sun
Li Wang
Haojie Yu
Yongsheng Zain-ul-Abdin
Hamad Chen
Nasir Khalid
Muhammad Abbasi
机构
[1] Zhejiang University,State Key Laboratory of Chemical Engineering, Department of Chemical and Biological Engineering
来源
Journal of Inorganic and Organometallic Polymers and Materials | 2014年 / 24卷
关键词
Ferrocene-based hyperbranched polyethers; Burning rate catalyst; Thermal decomposition; Ammonium perchlorate;
D O I
暂无
中图分类号
学科分类号
摘要
A series of ferrocene-based hyperbranched polyethers (HBPE-Fc) with different ferrocene content were synthesized by esterification of ferrocenecarbonyl chloride and hyperbranched polyether (HBPE). 1H NMR and FT-IR were used to confirm the structure of HBPE and HBPE-Fc. GPC was used to calculate the molecular weights. The catalytic performance of the synthesized HBPE-Fc for thermal decomposition of ammonium perchlorate (AP) was investigated by TG and DTG techniques. The results showed that HBPE-Fc exhibited good catalytic activity on the thermal decomposition of AP. The influence factors on catalytic performances, such as substitution degree of ferrocene and mass ratio of AP/HBPE-Fc were discussed as well.
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页码:1063 / 1069
页数:6
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