The lead(II) complexes with 18-Crown-6, 1,1,1,5,5,5-hexafluoropentane-2,4-dionate and 1,1,1-trifluoropentate-2,4-dionate anions: Synthesis, structure, and thermochemical properties

被引：0
作者：
V. G. Sevast’yanov
M. A. Chistyakov
E. P. Simonenko
G. K. Fukin
N. T. Kuznetsov
机构：
[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry
[2] Russian Academy of Sciences,Razuvaev Institute of Organometallic Chemistry
来源：
Russian Journal of Coordination Chemistry | 2008年 / 34卷
关键词：
Crown Ether; Coordination Chemistry; Vaporization Enthalpy; Macrocycle Cavity; Analogous Distance;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The complexes trans-[Pb(18-crown-6)(NO3)2] (I), trans-[Pb(18-crown-6)(Hfa)2] (II), and [Pb2(18-crown-6)(Tfa)4] (III), where Hhfa is 1,1,1,5,5,5-hexafluoropentane-2,4-dione and Htfa is 1,1,1-trifluoropentane-2,4-dione, were synthesized and identified. The structures of crystals I–III were determined by X-ray diffraction, whereas the melting and decomposition of compounds II, III were studied by the differential scanning calorimetry. The temperature of preparative sublimation of complexes II, III was determined at 10−2 mm Hg. The semiempirical structural-thermochemical approach was used to analyze the parameters of complex II vaporization.
引用
收藏
页码：157 / 166
页数：9
相关论文
共 8 条
[1]   Synthesis, structure and thermochemical behavior of bis-(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)-(1,4,7,10,13,16-hexaoxa-cyclooctadecane)-strontium in comparison with its structural and thermochemical analogous [J].
Polyanskaya, Tamara M. ;
Chistyakov, Mikhail A. ;
Simonenko, Elizaveta P. ;
Sevast'anov, Vladimir G. ;
Kuznetsov, Nikolay T. .
INORGANICA CHIMICA ACTA, 2009, 362 (15) :5133-5138
[2]   Synthesis and structure of supramolecular complexes between 1-alkynyl(phenyl)(tetrafluoroborato)-λ3-iodanes and 18-crown-6 [J].
Ochiai, M ;
Miyamoto, K ;
Suefuji, T ;
Shiro, M ;
Sakamoto, S ;
Yamaguchi, K .
TETRAHEDRON, 2003, 59 (51) :10153-10158
[3]   Crystal structures of molecular complexes of 18-crown-6 with 2-aminobenzoic and 5-amino-1-benzyl-1,2,3-triazole-4-carboxylic acid hydrazides [J].
Simonov, YA ;
Fonar', MS ;
Kravtsov, VC ;
Lipkowski, J ;
Ganin, ÉV ;
Yavolovskii, AA .
CRYSTALLOGRAPHY REPORTS, 2002, 47 (01) :86-93
[4]   Crystal structures of molecular complexes of 18-crown-6 with 2-aminobenzoic and 5-amino-1-benzyl-1,2,3-triazole-4-carboxylic acid hydrazides [J].
Yu. A. Simonov ;
M. S. Fonar’ ;
V. Ch. Kravtsov ;
J. Lipkowski ;
É. V. Ganin ;
A. A. Yavolovskii .
Crystallography Reports, 2002, 47 :86-93
[5]   Synthesis, X-ray investigation and DFT calculations of solvated barium β-diketonate complexes with 18-dibenzocrown-6: [Ba(pta)2(18DBC6)](C6H5CH3)2 and [Ba(pta)2(18DBC6)](CH2Cl2) (pta=1,1,1-trifluoro-5,5-dimethylhexanedionato-2,4; 18DBC6=18-dibenzocrown-6) [J].
Pochekutova, Tatjana S. ;
Khamylov, Vyacheslav K. ;
Ketkov, Sergey Yu ;
Fukin, Georgy K. ;
Khamaletdinova, Nadia M. ;
Petrov, Boris I. ;
Kuznetsova, Olga V. .
POLYHEDRON, 2014, 79 :229-238
[6]   Synthesis and properties of novel crown ether-annelated 4′,5′-diaza-9′-(1,3-dithiole-2-ylidene)-fluorenes and their ruthenium(II) complexes [J].
Sako, Katsuya ;
Kakehi, Toshiaki ;
Nakano, Shota ;
Oku, Hiroyuki ;
Shen, Xu Feng ;
Iwanaga, Tetsuo ;
Yoshikawa, Manami ;
Sugahara, Kouta ;
Toyota, Shinji ;
Takemura, Hiroyuki ;
Shinmyozu, Teruo ;
Shiotsuka, Michito ;
Tatemitsu, Hitoshi .
TETRAHEDRON LETTERS, 2014, 55 (03) :749-752
[7]   Binuclear copper(II) complexes of Schiff base ligand derived from 1-phenyl-3-methyl-4-formylpyrazol-5-one and 1,3-diaminopropan-2-ol: Synthesis, structure and magnetic properties [J].
Popov, Leonid D. ;
Levchenkov, Sergey I. ;
Shcherbakov, Igor N. ;
Lukov, Vladimir V. ;
Suponitsky, Kyrill Y. ;
Kogan, Victor A. .
INORGANIC CHEMISTRY COMMUNICATIONS, 2012, 17 :1-4
[8]   Synthesis, crystal structure, and magnetic properties of binuclear cobalt(II) complex with 2-(5-{6-[5-(pyrazin-2-yl)-1H-1,2,4-triazol-3-yl]-pyridin-2-yl}-1H-1,2,4-triazol-3-yl)pyrazine [J].
X. Y. Huang ;
Q. Q. Jiang ;
J. S. Zhao ;
S. C. Zhang ;
J. L. Wang .
Russian Journal of Coordination Chemistry, 2015, 41 :202-206
1