Role of chain termination in the suppressing effect of hydrocarbons on the combustion of hydrogen-air mixtures

被引:0
|
作者
V. V. Azatyan
V. I. Kalachev
V. V. Masalova
机构
[1] Russian Academy of Sciences,Institute of Structural Macrokinetics and Materials Research Problems
来源
Kinetics and Catalysis | 2006年 / 47卷
关键词
Combustion; Combustion Rate; Detonation Wave; Chain Termination; Hydrogen Combustion;
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学科分类号
摘要
In the inhibition of the combustion of hydrogen-oxygen mixtures, the consumption of O2 by the inhibitor is only due to preliminary reactions between the inhibitor and active intermediates of H2 combustion. These reactions result in chain termination. The inhibiting effect of an admixture is determined by its chain-terminating capacity. The denial of the inhibiting effect by some authors is, in essence, the denial of the chain nature of combustion.
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页码:481 / 486
页数:5
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