Techno-economic analysis of biocatalytic processes for production of alkene epoxides

被引：0
作者：
Abhijeet P. Borole
Brian H. Davison
机构：
[1] Oak Ridge National Laboratory,Life Biosciences Division
来源：
Applied Biochemistry and Biotechnology | 2007年 / 137-140卷
关键词：
Bioprocess; chloroperoxidase; economics; enzymatic; epoxides; lipase;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A techno-economic analysis of two different bioprocesses was conducted, one for the conversion of propylene to propylene oxide (PO) and other for conversion of styrene to styrene epoxide (SO). The first process was a lipase-mediated chemo-enzymatic reaction, whereas the second one was a one-step enzymatic process using chloroperoxidase. The PO produced through the chemo-enzymatic process is a racemic product, whereas the latter process (based on chloroperoxidase) produces an enantio-pure product. The former process thus falls under the category of high-volume commodity chemical (PO); whereas the latter is a low-volume, high-value product (SO).
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页码：437 / 449
页数：12
相关论文
共 90 条
  • [11] Sakoguchi A.(1992)undefined Tetrahedron 48 4587-4592
  • [12] Nakashio F.(1990)undefined J. Chem. Soc. Chem. Commun. 19 1301-1303
  • [13] Goto M.(1997)undefined J. Mol. Catalysis a-Chem. 117 311-319
  • [14] Song B. D.(1997)undefined Ann. Rev. Microbiol. 51 491-525
  • [15] Ding H.(1998)undefined Appl. Biochem. Biotechnol. 74 115-123
  • [16] Wu J. C.(2001)undefined Chem. Eng. Sci. 56 427-432
  • [17] Hayashi Y.(1999)undefined Ind. Crops Prod. 9 125-132
  • [18] Talukder M.(2006)undefined Biotechnol. Bioeng. 93 1190-1195
  • [19] Wang S. C.(2006)undefined Biotechnol. Bioeng. 94 189-192
  • [20] Mine Y.(2002)undefined Biotechnol. Bioeng. 80 33-41
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