Synthesis, crystal structure, and luminescence properties of complexes (4-ViBnNMe3)2[{M6(µ3-I)8}I6] (M = Mo, W; (4-ViBnNMe3)+ is trimethyl(4-vinylbenzyl)ammonium)

被引：0
作者：
Yu. A. Vorotnikov
M. A. Mikhailov
K. A. Brylev
D. A. Piryazev
N. V. Kuratieva
M. N. Sokolov
Yu. V. Mironov
M. A. Shestopalov
机构：
[1] Siberian Branch of the Russian Academy of Sciences,A. V. Nikolaev Institute of Inorganic Chemistry
[2] Novosibirsk State University,undefined
[3] Scientific Institute of Clinical and Experimental Lymphology,undefined
来源：
Russian Chemical Bulletin | 2015年 / 64卷
关键词：
molybdenum; tungsten; octahedral cluster complexes; crystal structure; luminescence;
D O I：
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中图分类号：
学科分类号：
摘要：
Two new compounds based on octahedral molybdenum and tungsten iodide cluster complexes of the composition (4-ViBnNMe3)2[{M6(µ3-I)8}I6] (M = Mo, W; (4-ViBnNMe3)+ is trimethyl(4-vinylbenzyl)ammonium) were synthesized and structurally characterized. The luminescence properties of powder samples of the synthesized compounds and of the salts (Bu4N)2[{M6(µ3-I)8}I6] described earlier were investigated. Due to the presence of the vinylcontaining cation, these compounds can be involved in radical copolymerization in order to produce polymeric luminescent materials.
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页码：2591 / 2596
页数：5
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