The stereoselectivity of the pinacol-coupling of various substituted benzaldehydes mediated by samarium diiodide was investigated. The dependence of product-ratios, yields, and stereoselectivities on the substrate, the substrate-reagent-ratio, and the solvent is described.
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Zhejiang Normal Univ, Coll Chem & Life Sci, Zhejiang 321004, Peoples R ChinaZhejiang Normal Univ, Coll Chem & Life Sci, Zhejiang 321004, Peoples R China
Zhu, CL
Wang, XX
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Zhejiang Normal Univ, Coll Chem & Life Sci, Zhejiang 321004, Peoples R ChinaZhejiang Normal Univ, Coll Chem & Life Sci, Zhejiang 321004, Peoples R China