Stereoselectivity in Pinacol-Homocoupling Mediated by Samarium Diiodide

被引：0
|
作者：
Peter Gärtner
Max Knollmüller
Joachim Bröker
机构：
[1] Institute of Applied Synthetic Chemistry,
[2] Vienna University of Technology,undefined
[3] A-1060 Vienna,undefined
[4] Austria,undefined
来源：
Monatshefte für Chemie / Chemical Monthly | 2003年 / 134卷
关键词：
Keywords. Lanthanides; Aldehydes; Reductions; Hydrobenzoin; Diastereoselectivity.;
D O I：
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中图分类号：
学科分类号：
摘要：
 The stereoselectivity of the pinacol-coupling of various substituted benzaldehydes mediated by samarium diiodide was investigated. The dependence of product-ratios, yields, and stereoselectivities on the substrate, the substrate-reagent-ratio, and the solvent is described.
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页码：1607 / 1615
页数：8
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