Kinetics and mechanism of nickel reaction with benzyl bromide in dimethylformamide

被引：0
作者：
A. M. Egorov
S. A. Matyukhova
I. S. Kocherova
A. A. Novikova
A. V. Anisimov
机构：
[1] Tula State University,
[2] Lomonosov Moscow State University,undefined
来源：
Russian Journal of General Chemistry | 2009年 / 79卷
关键词：
General Chemistry; Benzyl Bromide; Chromatomass Spectrometry; TMPO; Dimethylbiphenyl;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The reaction of nickel with benzyl bromide in DMF has been studied. The reaction intermediates were investigated by different methods and the kinetic and thermodynamic parameters were determined. The reaction of benzyl bromide with nickel was shown to occur on the metal surface by the Langmuir-Hinshelwood scheme, with the formation of benzyl radicals which are recombined and isomerized in solution to form 1,2-diphenylethane and trace amounts of 4.4′-dimethylbiphenyl.
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页码：444 / 452
页数：8
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