Assessment of process parameters on the production of diglycerides rich in omega-3 fatty acids through the enzymatic glycerolysis of fish oil

被引:0
作者
Maria Manuela Camino Feltes
J. Vladimir Oliveira
Helen Treichel
Jane Mara Block
Débora de Oliveira
Jorge Luiz Ninow
机构
[1] Universidade Federal de Santa Catarina,Departamento de Engenharia Química e de Alimentos
[2] UFSC,Programa de Pós
[3] Universidade Regional Integrada do Alto Uruguai e das Missões,Graduação em Engenharia de Alimentos
[4] Universidade Federal de Santa Catarina,Departamento de Ciência de Alimentos
[5] UFSC,undefined
来源
European Food Research and Technology | 2010年 / 231卷
关键词
Glycerolysis; Fish oil; Lipases; Diglycerides;
D O I
暂无
中图分类号
学科分类号
摘要
The main objective of this work is to present new experimental information concerning the effect of relevant process parameters related to the production of diglycerides by enzymatic glycerolysis of fish oil. Reaction products can be applied as ingredients in food industry, joining the emulsifying properties of partial glycerides along with the nutritional benefits attributed to the omega-3 fatty acids. From preliminary reactions, conversion was higher for a solvent- and surfactant-free system but the long time to reach appreciable amounts of diglycerides may be a drawback for practical purposes. To overcome this problem, the addition of tert-butanol revealed to be relevant, leading to high diglycerides contents in short times. The system containing Tween 65 led to the highest amount of diglycerides. This study described the feasibility of enzymatic synthesis of diglycerides rich in EPA and DHA in short reaction times as well by using a more environmentally friendly process.
引用
收藏
页码:701 / 710
页数:9
相关论文
共 67 条
  • [1] Damstrup ML(2005)Solvent optimization for efficient enzymatic monoacylglycerol production based on a glycerolysis reaction J Am Oil Chem Soc 82 559-564
  • [2] Jensen T(2006)Production of heat-sensitive monoacylglycerols by enzymatic glycerolysis in tert-pentanol: process optimization by response surface methodology J Am Oil Chem Soc 83 27-33
  • [3] Sparsø FV(2007)Synthesis of monoacylglycerol rich in polyunsaturated fatty acids from tuna oil with immobilized lipase AK Food Chem 104 251-258
  • [4] Kiil SZ(1995)Lipase-catalyzed syntheses of monoacylglycerols Enzyme Microb Technol 17 578-586
  • [5] Jensen AD(1999)Enzymes as biocatalysts in the modification of natural lipids Rev J Sci Food Agric 79 1535-1549
  • [6] Xu X(2002)Lipase-catalyzed glycerolysis of an oil rich in eicosapentaenoic acid residues Biotechnol Lett 24 667-673
  • [7] Damstrup ML(2009)Kinetics of solvent-free lipase catalyzed production of monoacylglycerols from olive oil in Aerosol-OT surfactant Ind Eng Chem Res 48 708-712
  • [8] Jensen T(2006)Assessment of two immobilized lipases activity treated in compressed fluids J Supercritic Fluid 38 373-382
  • [9] Sparsø FV(2005)Monoacylglycerol synthesis via enzymatic glycerolysis using a simple and efficient reaction system J Food Lipid 12 299-312
  • [10] Kiil SZ(2008)Physico-enzymatic production of monoacylglycerols enriched with very-long-chain polyunsaturated fatty acids J Sci Food Agric 88 256-262