Sol-gel Preparation of Rutile Type Solid Solution in TiO2-RuO2 System

被引：0

作者：

J. Málek

A. Watanabe

T. Mitsuhashi

机构：

[1] Academy of Sciences of the Czech Republic and University of Pardubice,Joint Laboratory of Solid State Chemistry

[2] National Institute for Research in Inorganic Materials,undefined

[3] Science and Technology Agency of Japan,undefined

来源：

Journal of Thermal Analysis and Calorimetry | 2000年 / 60卷

关键词：

crystallization kinetics; sol-gel; solid solutions; ruthenia; titania;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The preparation of rutile type solid solutions in (TiO2)x -(RuO2)1−x system in the 0≤x ≤0.7 concentration range is described. The single phase solid solutions are formed by controlled nanocrystallization of amorphous gels prepared by the sol-gel method. The kinetics of this crystallization process has been analyzed. It was found that the crystallization does not correspond to the Johnson-Mehl-Avrami model and it can be described by the two-parameter Šesták-Berggren kinetic model.

引用

页码：699 / 705

页数：6

共 41 条

[1]

Blondeel G.(1983)undefined J. Phys. Chem. 87 2629-undefined

[2]

Harrlman A.(1984)undefined J. Am. Chem. Soc. 106 1504-undefined

[3]

Porter G.(1987)undefined Nature 327 506-undefined

[4]

Urwin D.(1989)undefined Cryst. Res. Technol. 24 1009-undefined

[5]

Kiwi J.(1993)undefined Phys. Rev. B 47 12550-undefined

[6]

Baltzer P.(1983)undefined Matt. Res. Bull. 18 677-undefined

[7]

Davidson R. S.(1977)undefined Russ. J. Inorg. Chem. 22 110-undefined

[8]

Tseung A. C.(1977)undefined Russ. J. Inorg. Chem. 22 273-undefined

[9]

Grätzel M.(1988)undefined Sci. Papers. Inst. Chem. Technol. Pardubice 52 27-undefined

[10]

Kiwi J.(1994)undefined Mater. Chem. Phys. 38 305-undefined

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