Improvement of acid modification and its effect on the adsorption of stearic acid into sepiolite

被引:0
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作者
Wen-Tao Yan
Wei-Biao Ye
Juan Du
Yuxiang Hong
机构
[1] Xiangtan University,Department of Process Equipment and Control Engineering, School of Mechanical Engineering
[2] Guangxi University of Science and Technology,School of Biological and Chemical Engineering
[3] Lishui University,Department of Chemistry and Chemical Engineering
关键词
Form-stable PCMs; Stearic acid; Modified sepiolite; Phase change energy storage;
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学科分类号
摘要
To improve sepiolite's ability to absorb stearic acid, different hydrochloric acid modification conditions were used to modify sepiolite. Stearic acid was encapsulated by direct dipping modified sepiolite. The leakage test was carried out. The crystal structure, microstructure, latent heat, thermal stability and thermal conductivity were characterized. The improved acidification condition of 4 mol L−1 for hydrochloric acid concentration, 6 h for acidification time and 313.15 K for acidification temperature can improve the load rate of stearic acid for 5 mass% relative to previous experimental data, the load mass fraction of stearic acid can reach to 40%. The composite prepared by improving acidification conditions has higher latent heat of melting and solidification of 74.66 J g−1 at 346.65 K and 77.02 J g−1 at 332.05 K, respectively. The composite phase change materials prepared by physical stirring have good chemical compatibility and thermal durability.
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页码:3025 / 3032
页数:7
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