Feasibility Study of Introducing Redox Property by Modification of PMBN Polymer for Biofuel Cell Applications

被引：0
|
作者：
Eileen Hao Yu
Yoko Himuro
Madoka Takai
Kazuhiko Ishihara
机构：
[1] Newcastle University,School Chemical Engineering and Advanced Materials, Merz Court
[2] The University of Tokyo,Department of Materials Engineering
来源：
Applied Biochemistry and Biotechnology | 2010年 / 160卷
关键词：
PMBN polymer; PQQ; Redox property; Enzyme immobilization; Glucose oxidation; Enzymatic biofuel cells;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
In this study, the feasibility of introducing redox property to an amphiphilic phospholipid polymer (PMBN) was investigated. The active ester group in the side chain of the polymer was used to react with pyrroloquinoline quinine (PQQ). Redox peaks that corresponded to PQQ redox potentials were observed after the modification. Glucose oxidase was immobilized to the modified polymer. Electrochemical oxidation of glucose was carried out with the polymer electrode. The oxidation current increased with elevating glucose concentration indicating electron transfer established between the electrode and enzyme. It suggests that by modification, PMBN is possible to use for enzyme electrode for bioelectronics.
引用
收藏
页码：1094 / 1101
页数：7
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