Reactions of p-toluenesulfenyl chloride with enol acetates. The synthetic potential of the resulting adducts

被引:0
作者
W. A. Smit
E. A. Yagodkin
G.V. Zatonsky
机构
[1] Russian Academy of Sciences,N. D. Zelinsky Institute of Organic Chemistry
来源
Russian Chemical Bulletin | 2005年 / 54卷
关键词
enol acetates; arenesulfenyl chlorides; electrophilic addition; C-nucleophiles; β-arylthioalkylation;
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中图分类号
学科分类号
摘要
Reactions of vinyl and propen-2-yl acetates with p-toluenesulfenyl chloride afforded the corresponding α-chloro-β-(p-tolyl)thioalkyl acetates in nearly quantitative yields.These adducts reacted with some C-nucleophiles in the presence of Lewis acids to give the corresponding alkylation products.
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页码:743 / 747
页数:4
相关论文
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