Synthetic Transformations of Higher Terpenoids: IX. Nitrogen-Containing Heterocyclic Compounds on the Basis of Lambertianic Acid

被引：0

作者：

S. V. Chernov

E. E. Shul’ts

M. M. Shakirov

I. Yu. Bagryanskaya

Yu. V. Gatilov

G. A. Tolstikov

机构：

[1] Russian Academy of Sciences,Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Division

来源：

Russian Journal of Organic Chemistry | 2005年 / 41卷

关键词：

Oxidation; Methyl; Ester; Formaldehyde; Organic Chemistry;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Oxidation of lambertianic acid methyl ester and methyl 15,16-epoxy-17-hydroxylabda-13(16)14-dien-18-oate gave 17-nor-8-oxo-, 8,12-epoxy-17-hydroxy-, and 8-formyl-17-norlabdadienoic acid esters which were subjected to reductive amination, and the subsequent intramolecular aminomethylation of 17-nor-8(R)-methylamino- and 17-methylaminolabdadienoates with formaldehyde afforded new polycyclic compounds, furoazocine and furoazonine derivatives.

引用

页码：535 / 545

页数：10

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