Radial distribution function of rod-like polyelectrolytes

被引:0
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作者
R. Zandi
J. Rudnick
R. Golestanian
机构
[1] Department of Chemistry and Biochemistry,
[2] UCLA,undefined
[3] Box 951569,undefined
[4] Los Angeles,undefined
[5] CA 90095-1569,undefined
[6] USA,undefined
[7] Department of Physics and Astronomy,undefined
[8] UCLA,undefined
[9] Box 951547,undefined
[10] Los Angeles,undefined
[11] CA 90095-1547,undefined
[12] USA,undefined
[13] Institute for Advanced Studies in Basic Sciences,undefined
[14] Zanjan 45195-159,undefined
[15] Iran,undefined
[16] Institute for Studies in Theoretical Physics and Mathematics,undefined
[17] P.O. Box 19395-5531,undefined
[18] Tehran,undefined
[19] Iran,undefined
来源
关键词
PACS. 82.35.Rs Polyelectrolytes – 87.15.La Mechanical properties – 36.20.-r Macromolecules and polymer molecules;
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学科分类号
摘要
We study the effect of electrostatic interactions on the distribution function of the end-to-end distance of a single polyelectrolyte chain in the rod-like limit. The extent to which the radial distribution function of a polyelectrolyte is reproduced by that of a wormlike chain with an adjusted effective persistence length is investigated. Strong evidence is found for a universal scaling formula connecting the effective persistence length of a polyelectrolyte with the strength of the electrostatic interaction and the Debye screening length.
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页码:41 / 46
页数:5
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