Description of electrochemical reactions at electrode-electrolyte interface as boundary conditions in case of mathematical simulation of processes in flow 3D electrode

被引：0
作者：
A. N. Koshev
V. K. Varentsov
机构：
[1] Penza State University of Architecture and Building,Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch
[2] Novosibirsk State Technical University,undefined
[3] Russian Academy of Sciences,undefined
来源：
Russian Journal of Electrochemistry | 2014年 / 50卷
关键词：
mathematical simulation; boundary conditions; electrochemical reactions; polarization dependences;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The work considers descriptions of electrode reactions in the context of their application as boundary conditions in solution of problems of calculation of processes in electrochemical reactions. Methods of setting polarization curve equations under changing conditions of occurrence of electrochemical reactions are presented, in particular for the dependence of equilibrium potential and exchange current on the concentration of the electroactive component. The effect of hydrodynamic conditions on the polarization dependence of current density on potential is considered in a flow 3D electrode.
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页码：846 / 851
页数：5
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