Surface modification of polypropylene film by grafting with vinyl monomers for the attachment of chitosan

被引:0
作者
K. S. Abudonia
G. R. Saad
H. F. Naguib
M. Eweis
D. Zahran
M. Z. Elsabee
机构
[1] Cairo University,Chemistry Department, Faculty of Science
[2] Cairo University,Department of Botany and Microbiology, Faculty of Science
来源
Journal of Polymer Research | 2018年 / 25卷
关键词
PP film; Corona; Acrylic acid; Methyl methacrylate; Grafting; Chitosan; Antimicrobial activity;
D O I
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中图分类号
学科分类号
摘要
Polypropylene (PP) film activated by corona discharge treatment was grafted with methyl methacrylate (MMA) and acrylic acid (AA). The grafted PP was characterized by spectral, thermal analysis and swelling behavior which confirmed the occurrence of the grafting. The water vapor and oxygen permeability (OTR and WVTR) as well as the mechanical properties have been enhanced by grafting with both AA and MMA. The grafted PP was further immobilized with chitosan (CS) using ceric ammonium nitrate (CAN) as an initiator under ultraviolet radiation. The chitosan immobilized grafted film was characterized by FTIR, mechanical properties, thermal properties and swelling measurements. Scanning electron microscope (SEM) confirmed that the CS is bonded to the grafted PP film. The CS modified PP film has acquired enhanced antibacterial and antifungal properties.
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