Surface modification of polypropylene film by grafting with vinyl monomers for the attachment of chitosan

被引：0
作者：
K. S. Abudonia
G. R. Saad
H. F. Naguib
M. Eweis
D. Zahran
M. Z. Elsabee
机构：
[1] Cairo University,Chemistry Department, Faculty of Science
[2] Cairo University,Department of Botany and Microbiology, Faculty of Science
来源：
Journal of Polymer Research | 2018年 / 25卷
关键词：
PP film; Corona; Acrylic acid; Methyl methacrylate; Grafting; Chitosan; Antimicrobial activity;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Polypropylene (PP) film activated by corona discharge treatment was grafted with methyl methacrylate (MMA) and acrylic acid (AA). The grafted PP was characterized by spectral, thermal analysis and swelling behavior which confirmed the occurrence of the grafting. The water vapor and oxygen permeability (OTR and WVTR) as well as the mechanical properties have been enhanced by grafting with both AA and MMA. The grafted PP was further immobilized with chitosan (CS) using ceric ammonium nitrate (CAN) as an initiator under ultraviolet radiation. The chitosan immobilized grafted film was characterized by FTIR, mechanical properties, thermal properties and swelling measurements. Scanning electron microscope (SEM) confirmed that the CS is bonded to the grafted PP film. The CS modified PP film has acquired enhanced antibacterial and antifungal properties.
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[1]  
Fasce LA(2008)Poly (acrylic acid) surface grafted polypropylene films: Near surface and bulk mechanical response Express Polym Lett 2 779-790
[2]  
Costamagna V(2010)Chitosan immobilization on polyacrylic acid grafted polypropylene monofilament Carb Polym 82 1315-1322
[3]  
Pettarin V(2000)Gama radiation-induced graft copolymerization of N-p-hydroxyphenylmaleimide onto polypropylene films J Polym Res 7 215-219
[4]  
Strumia M(2007)Surface enrichment of polypropylene-graft-poly(methyl methacrylate) on polypropylene J Polym Res 14 489-2193
[5]  
Frontini PM(2011)Grafting modification and properties of polypropylene with pentaerythritol tetra-acrylate J Polym Res 18 2185-830
[6]  
Saxena S(2003)Gamma radiation induced graft copolymerization of vinylimidazole-acrylic acid onto polypropylene films Polymer Testing 22 825-234
[7]  
Ray AR(1997)Graft copolymers of polypropylene films. 1. Radiation-induced grafting of mixed monomers Polymer International 42 225-940
[8]  
Gupta B(2008)Radiation grafting of N,N′-dimethylacrylamide and N-isopropylacrylamide onto polypropylene films by two-step method J Rad Phys Chem 77 936-186
[9]  
Mokhtar SM(2007)Radiation-induced grafting of N-isopropylacrylamide and acrylic acid onto polypropylene films by two step method Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms. 265 183-9
[10]  
Mostafa TB(2013)Preparation and characterization of acrylic acid(AA) and 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPS) grafted polypropylene by two-steps electron beam irradiation for filtration of cigarette smoke J Polym Res 20 44-347
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