Effect of Regime of Addition of Initiator on TEMPO-Mediated Polymerization of Styrene

被引:0
作者
F. Díaz-Camacho
S. López-Morales
E. Vivaldo-Lima
E. Saldívar-Guerra
R. Vera-Graziano
L. Alexandrova
机构
[1] Instituto de Investigaciones en Materiales,Facultad de Química
[2] Universidad Nacional Autónoma de México,undefined
[3] Centro de Investigación en Química Aplicada,undefined
来源
Polymer Bulletin | 2004年 / 52卷
关键词
Polymerization; Styrene; AIBN; Significant Acceleration; Specific Regime;
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学科分类号
摘要
Investigation of the TEMPO-mediated polymerization of styrene at different regimes of addition of AIBN initiator showed that the course of the polymerization could be changed dramatically by a mode of the initiator addition without using any other additives. A very significant acceleration of the polymerization was reached at a specific regime without broadening the polydispersity of the resulting polymer.
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页码:339 / 347
页数:8
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