Cobalt(II), nickel(II), and copper(II) complexes with Schiff bases, derivatives of 1-amino-8-hydroxynaphthalene-2,4-disulfonic acid

被引：0

作者：

L. S. Skorokhod

I. I. Seifullina

V. G. Vlasenko

I. V. Pirog

V. V. Minin

机构：

[1] Mechnikov National University,Research Institute of Physics

[2] Rostov State University,Kurnakov Institute of General and Inorganic Chemistry

[3] Russian Academy of Sciences,undefined

来源：

Russian Journal of Inorganic Chemistry | 2007年 / 52卷

关键词：

Schiff Base; XANES Spectrum; Benzoin; Sulfo Group; Disulfonic Acid;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Five new cobalt(II), nickel(II), and copper(II) complexes with Schiff bases have been synthesized. The Schiff bases have been prepared by the condensation of monopotassium 1-amino-8-hydroxynaphthalene-2,4-disulfonate with benzoin (L1) or 2-hydroxy-1-naphthaldehyde (L2). The compounds have been identified and studied by elemental analysis, X-ray diffraction, thermogravimetry, measurements of magnetic susceptibility and electrical conductivity, and IR, ESR, and diffuse reflectance spectroscopy. The dimeric (with oxo bridges) structure of the Co(II) complex with L1 has been additionally confirmed by the EXAFS method.

引用

页码：1395 / 1401

页数：6

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