A facile access for the C-N bond formation by transition metal-free oxidative coupling of benzylic C-H bonds and amides

被引：0

作者：

Jie Liu

Heng Zhang

Hong Yi

Chao Liu

Aiwen Lei

机构：

[1] Wuhan University,College of Chemistry and Molecular Sciences

[2] Jiangxi Normal University,National Research Centre for Carbohydrate Synthesis

来源：

Science China Chemistry | 2015年 / 58卷

关键词：

oxidative coupling; C-N bond formation; amination; C-H functionalization;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Using 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) as the oxidant, we communicate an efficient oxidative C-N coupling of benzylic C-H bonds with amides to afford a series of amination products in good yields. A wide range of functional groups as well as various sulfonamides and carboxamides are well tolerated. Moreover, this reaction involves both the challenging C-H functionalization and C-N bond formation.

引用

页码：1323 / 1328

页数：5

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