Differential pulse stripping voltammetric determination of heavy metals simultaneously using new polymer modified glassy carbon electrodes

被引:1
作者
Paramasivam Manisankar
Chinnapiyan Vedhi
Ganesan Selvanathan
Perumal Arumugam
机构
[1] Alagappa University,Department of Industrial Chemistry
[2] V.O. Chidambaram College,Department of Chemistry
[3] AVC College (Autonomous),Department of Chemistry
[4] Tamil Nadu Pollution Control Board,District Environmental Laboratory
来源
Microchimica Acta | 2008年 / 163卷
关键词
Heavy metals; Stripping voltammetry; Glassy carbon electrode; Polymer modified electrode; Poly(3; 4-ethylenedioxythiophene);
D O I
暂无
中图分类号
学科分类号
摘要
Seven novel polymer modified glassy carbon electrodes have been developed for the analysis of metals of zinc, cadmium, lead, arsenic and copper in formulated samples of waters and industrial wastewater samples by differential pulse stripping voltammetry. Very good responses have been observed for all the metals with all the modified electrodes employed. However, the poly(3,4-ethylenedioxythiophene) modified electrode has resulted in very low detection limits. An independent atomic absorption spectroscopic analysis of the industrial wastewater sample was carried out and the results are compared.
引用
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页码:289 / 295
页数:6
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共 117 条
[1]  
Gerard M(2002)Application of conducting polymers to biosensors Biosens Bioelectron 17 345-3291
[2]  
Chaubey A(2004)Conductive copolymer-modified carbon fibre microelectrodes: electrode characterisation and electrochemical detection of paminophenol Sens Actuators, B 97 59-undefined
[3]  
Malhotra BD(1991)The use of electropolymerization to produce new sensing surfaces: a review emphasizing electrodeposition of heteroaromatic compounds Electroanalysis 3 879-undefined
[4]  
Jamal M(1994)Poly(3,3′-diaminobenzidine) film on a gold electrode for selective preconcentration and stripping analysis of selenium(IV) Anal Chem 66 4543-undefined
[5]  
Sarac AS(1995)Factors affecting the electroanalytical behavior of polypyrrole-modified electrodes bearing complexing ligands Anal Chem 67 2828-undefined
[6]  
Magner E(1985)Multiple-use polymer-modified electrodes for electroanalysis of metal ions in solution Anal Chem 57 2009-undefined
[7]  
Imisides MD(1986)Poly(pyrrole- Anal Chem 58 128-undefined
[8]  
John R(1988)-carbodithioate) electrode for electroanalysis J Electroanal Chem 247 145-undefined
[9]  
Riley PJ(1998)Preparation and application of conducting polymers containing chemically active counterions for analytical purposes J Electroanal Chem 448 25-undefined
[10]  
Wallace GG(1995)Electrochemical properties of cation sensitive polypyrrole films Bull Chem Soc Jpn 68 1297-undefined