Thermocatalytic decomposition of 1-methylcyclohexyl hydroperoxide

被引：0
作者：
A. M. Syroezhko
O. Yu. Begak
机构：
[1] St. Petersburg State Technological Institute,
[2] Mendeleev Russian Research Institute of Metrology,undefined
[3] Federal State Unitary Enterprise,undefined
来源：
Russian Journal of Applied Chemistry | 2004年 / 77卷
关键词：
Sodium; Mathematical Model; Hydroperoxide; Equilibrium Constant; Stearate;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A mathematical model of a multistage process of thermocatalytic decomposition of 1-methyl-cyclohexyl hydroperoxide in the presence of sodium stearate is developed. A procedure for calculating the unknown rate and equilibrium constants of the elementary and overall reaction stages is described. It is based on an analysis of the kinetic relationships in consumption of the initial products and accumulation of the intermediate and final products of thermocatalytic decomposition, with account of the known constants for individual stages.
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页码：1979 / 1986
页数：7
相关论文
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Syroezhko A.M.(1977)undefined Zh. Prikl. Khim. 50 1115-1119
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Proskuryakov V.A.(1976)undefined Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 19 1337-1339
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Syroezhko A.M.(undefined)undefined undefined undefined undefined-undefined
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Potekhin V.M.(undefined)undefined undefined undefined undefined-undefined
[8]  
Proskuryakov V.A.(undefined)undefined undefined undefined undefined-undefined
[9]  
Smirnov P.A.(undefined)undefined undefined undefined undefined-undefined
[10]  
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