X-Ray Crystal Structure of trans-PdCl2(PPh2C12H7S3)2, a New Morphology

被引：0

作者：

R. Dustan Myrex

Samuel B. Owens

Gary M. Gray

机构：

[1] University of Alabama at Birmingham,Department of Chemistry

来源：

Journal of Chemical Crystallography | 2007年 / 37卷

关键词：

Thiophene; Palladium; Phosphine; X-Ray; Single Crystal Structures; Conformation;

D O I：

暂无

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摘要：

Herein we report the crystal structure of trans-PdCl2(PPh2C12H7S3)2, 1, in a different morphology than has previously been reported [Stott et al. (Dalton Trans (4):652–653, 2005]. This structure crystallizes in a P-1 space group with a = 9.4249(19) Å, b = 11.540(2) Å, c = 12.559(3) Å, α = 79.07(3)°, β = 78.04(3)°, γ = 69.44(3)°, Z = 1. The earlier structure possessed a P21/n space group. Additionally the terthienyl moieties of 1 demonstrate the anti orientation exclusively while the P21/n space group structure has some syn and even syn/anti mixed geometries included.

引用

页码：549 / 553

页数：4