The thermodynamic properties of Fe(II) complexes with 1,2,4-triazoles

被引：0
作者：
G. A. Berezovskii
D. P. Pishchur
O. G. Shakirova
L. G. Lavrenova
机构：
[1] Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry, Siberian Division
来源：
Russian Journal of Physical Chemistry A | 2009年 / 83卷
关键词：
Heat Capacity; Htrz; Spin Transition; Mixed Ligand; Hexafluorosilicate;
D O I：
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学科分类号：
摘要：
The temperature dependences of the heat capacities at 106–330 K of the monoligand Fe(NH2trz)3I2 (I) and mixed-ligand Fe(Htrz)0.3(NH2trz)2.7SiF6 · H2O (II) complexes (Htrz is 1,2,4-triazole, and NH2trz is 4-amino-1,2,4-triazole) were studied by adiabatic vacuum calorimetry. The 1A1 ⇔ 5T2 spin transition was observed in these compounds. The thermodynamic parameters of phase transitions in I and II were determined.
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页码：1827 / 1831
页数：4
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