Density, refractive index, and viscosity of binary systems composed of ionic liquids ([Cnmim]Cl, n = 2, 4) and three dipolar aprotic solvents at T = 288.15–318.15 K

被引:0
作者
Lu Bai
Shu-Ni Li
Quan-Guo Zhai
Yu-Cheng Jiang
Man-Cheng Hu
机构
[1] Shaanxi Normal University,School of Chemistry and Chemical Engineering
[2] Key Laboratory of Macromolecular Science of Shaanxi Province,undefined
来源
Chemical Papers | 2015年 / 69卷
关键词
imidazolium-based ionic liquids; dipolar aprotic solvents; density; refractive index; viscosity;
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学科分类号
摘要
Thermophysical properties, such as density (ρ), refractive index (nD), and viscosity (η) of the binary systems of ionic liquids (ILs) [Cnmim]Cl (Cnmim = 1-alkyl-3-methylimidazolium; n = 2, 4) and three dipolar aprotic solvents (NMP (N-methyl-2-pyrrolidinone), DMI (1,3-dimethyl-2-imidazolidinone), and DMPU (1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone)) were measured based on the solubility of ILs in the molecular solvents at temperatures from 288.15 K to 318.15 K and the pressure of p = 0.1 MPa. Moreover, intermolecular interactions, such as weak hydrogen bonding and Coulomb forces, were discussed based on the determined properties.
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页码:1378 / 1388
页数:10
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