Thermodynamics of Mixed Ligand Complex Formation of Copper(II) and Nickel Ions with Glycine and Histidine in Solution

被引:0
作者
Dmitrii Pyréu
Sergei Gridchin
机构
[1] Ivanovo State University,Department of Inorganic and Analytic Chemistry
[2] Ivanovo State University of Chemistry and Technology,undefined
来源
Journal of Solution Chemistry | 2020年 / 49卷
关键词
Mixed-ligand complex formation; Calorimetry; Glycine; Histidine; Denticity;
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摘要
Mixed ligand complexes of copper(II) and nickel(II) with glycine (Gly) and histidine (His) have been studied in aqueous solution using calorimetric, potentiometric and spectrophotometric data at 298.15 K and the ionic strength of I = 0.5 mol·L–1 (KNO3). The thermodynamic parameters of formation of various mixed complexes have been determined. The probable coordination modes of amino acid residues in mixed ligand complexes is discussed.
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页码:239 / 253
页数:14
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  • [1] Block H(2009)Immobilized-metal affinity chromatography (IMAC): a review Methods Enzymol. 463 439-473
  • [2] Maertens B(1979)Histidine-containing ternary amino acid–copper(II) complexes. Syntheses and properties J. Am. Chem. Soc. 101 4164-4172
  • [3] Spriestersbach A(1994)Cu(II) binary and mixed-ligand binuclear complexes involving histidine as binucleating ligand J. Inorg. Biochem. 54 187-197
  • [4] Brinker N(1990)Non-covalent interactions in thermodynamic stereoselectivity of mixed-ligand copper(II)-D- or L-histidine complexes with L-amino acids. A possible model of metaI ion-assisted molecular recognition J. Chem. Soc Dalton Trans 1990 2095-2100
  • [5] Kubicek J(1980)pH-metric investigation of Cu(II) complexes with dipeptides Indian J. Chem. 19A 672-674
  • [6] Fabis R(1980)Solution equilibria of histidine-containing ternary amino acid copper(II) in 20 v/v% dioxane–water Bull. Chem. Soc. Jpn. 53 106-111
  • [7] Labahn J(1978)Mixed complexes of Ni(II) or Zn(II) with glycine and histamine or l-histidine in aqueous solution J. Inorg. Nucl. Chem. 40 1273-1276
  • [8] Schafer F(1980)pH-Metric studies on the mixed ligand complexes of Ni(II), Zn(II) & Cd(II) with histidine as a primary ligand & glycine & norleucine as secondary ligands Indian J. Chem. 19 922-924
  • [9] Yamauchi O(2005)Stability of copper(II), nickel(II) and zinc(II) binary and ternary complexes of histidine, histamine and glycine in aqueous solution J. Solution Chem. 34 213-231
  • [10] Sakurai T(1983)Spectroscopic analysis of binary and ternary copper(II) complexes formed by histidine and glutamic acid J. Coord. Chem. 12 213-218