Active Center Induced by Vibronic Interactions in V2O5/SiO2

被引：0
作者：
Tohru Sato
Naoya Iwahara
Ken Tokunaga
Kazuyoshi Tanaka
Tsunehiro Tanaka
机构：
[1] Kyoto University,Fukui Institute for Fundamental Chemistry
[2] Kyoto University,Department of Molecular Engineering, Graduate School of Engineering
[3] Core Research for Evolutional Science and Technology,Research and Development Center for Higher Education
[4] Japan Science and Technology Agency (JST-CREST),undefined
[5] Kyushu University,undefined
来源：
Topics in Catalysis | 2009年 / 52卷
关键词：
Vibronic coupling; Jahn-Teller effect; Photocatalyst; Vanadium oxide;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The vibronic interactions in a photocatalyst, isolated vanadium oxide on silica, is investigated theoretically employing a vibronic model. The T1 state gives rise to a Jahn-Teller distortion after the excitation. The HOMO is destabilized against the JT distortion, while the system is stabilized because of the JT effect.
引用
收藏
页码：808 / 812
页数：4
相关论文
共 42 条
[1]  
Yoshida S(1984)undefined J Chem Soc Faraday Trans 80 119-undefined
[2]  
Tanaka T(1986)undefined J Chem Soc Faraday Trans 82 35-undefined
[3]  
Okada M(2004)undefined Langmuir 20 4236-undefined
[4]  
Funabiki T(1992)undefined Catal Lett 12 277-undefined
[5]  
Tanaka T(2008)undefined Chem Phys Lett 460 478-undefined
[6]  
Ooe M(1975)undefined Chem Phys Lett 35 511-undefined
[7]  
Funabiki T(1985)undefined J Chem Soc Faraday Trans 81 1513-undefined
[8]  
Yoshida S(1995)undefined J Am Chem Soc 117 2618-undefined
[9]  
Amano F(1980)undefined J Phys Chem 84 3440-undefined
[10]  
Tanaka T(1983)undefined J Am Chem Soc 105 3719-undefined
12345