Characterization of Pt catalysts supported by three forms of TiO2 and their catalytic activities for hydrogenation

被引:0
作者
Huiqin An
Peng Hu
Xiaojing Hu
Weiling Zhao
Baolin Zhu
Shurong Wang
Shoumin Zhang
Weiping Huang
机构
[1] Tianjin Polytechnic University,School of Environmental and Chemical Engineering
[2] Nankai University,Department of Chemistry
来源
Reaction Kinetics, Mechanisms and Catalysis | 2013年 / 108卷
关键词
TiO; nanotubes; Pt; Cyclohexene; Hydrogenation; Catalytic performance;
D O I
暂无
中图分类号
学科分类号
摘要
Three forms of TiO2, commercial TiO2 powder, hydrogen titanate nanotubes obtained by hydrothermal treatment, and the thermally stable TiO2 nanotubes prepared by treating hydrogen titanate nanotubes with a sol containing titanium, were used as supports, and Pt nanoparticles were deposited on the supports via the photodeposition method. The catalytic performances of as-prepared and calcined Pt/TiO2 catalysts for the hydrogenation reaction of cyclohexene were evaluated. The results showed that the effects of the support and calcination temperature on the catalytic performances of Pt/TiO2 catalysts were obvious and significant. The thermally stable nanotubular TiO2-supported Pt catalyst exhibited better catalytic performance than the other TiO2-supported Pt catalysts. In addition, it was discovered that the calcination can enhance the catalytic activity of Pt/TiO2 for hydrogenation greatly.
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页码:117 / 126
页数:9
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