Reaction of methyl 1-bromocycloalkanecarboxylates with zinc and 2,6-bis(arylmethylene)cyclohexanones

被引:0
|
作者
N. F. Kirillov
A. G. Gavrilov
A. N. Vasyanin
S. N. Shurov
M. I. Vakhrin
P. A. Slepukhin
机构
[1] Perm State University,I.Ya. Postovsky Institute of Organic Synthesis
[2] Ural Branch of the Russian Academy of Sciences,undefined
来源
关键词
General Chemistry; Cyclohexanone; Cyclopentan; Tetrahydro; Benzylidene;
D O I
暂无
中图分类号
学科分类号
摘要
Methyl 1-bromocyclopentane-, 1-bromocyclohexane-, and 1-bromocycloheptanecarboxylates react with zinc and 2,6-bis(arylmethylene)cyclohexanones to afford 4-aryl-8-(arylmethylene)-5,6,7,8-tetrahydrospiro[chromene-3,1′-cyclopentan]-2(4H)-ones, 4-aryl-8-(arylmethylene)-5,6,7,8-tetrahydrospiro[chromene-3,1′-cyclohexan]-2(4H)-ones, and 4-aryl-8-(arylmethylene)-5,6,7,8-tetrahydrospiro[chromene-3,1′-cycloheptan]-2(4H)-ones, respectively.
引用
收藏
页码:289 / 293
页数:4
相关论文
共 50 条
  • [21] Reaction of 2,6-Bis(diazaboryl)pyridine with Alkyls of Lithium, Zinc and Magnesium
    Rommel, Valentin M. L.
    Fix, Jana M.
    Boettcher, Tobias
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2022, 648 (10):
  • [22] Double 1,3-dipolar cycloaddition of 2,6-bis(Arylmethylidene)cyclohexanones:: A novel entry into the synthesis of 2′,6′-bis-spiro(1-N-methyl-4-aryl- pyrrolidine)cyclohexanones
    Raj, AA
    Raghunathan, R
    SYNTHETIC COMMUNICATIONS, 2002, 32 (21) : 3295 - 3300
  • [23] Generalization of the anthocyanins kinetics and thermodynamics multistate to 2,6-bis(2-hydroxybenzylidene)cyclohexanones
    Alejo-Armijo, A.
    Moro, Artur J.
    Parola, A. Jorge
    Lima, Joao Carlos
    Pina, Fernando
    Corici, Livia
    Shova, Sergiu
    Cseh, Liliana
    DYES AND PIGMENTS, 2019, 163 : 573 - 588
  • [24] Asymmetrical 2,6-bis(benzylidene)cyclohexanones: Synthesis, cytotoxic activity and QSAR study
    Nakhjiri, Maryam
    Safavi, Maliheh
    Alipour, Eskandar
    Emami, Saeed
    Atash, Amir Farzin
    Jafari-Zavareh, Mona
    Ardestani, Sussan K.
    Khoshneviszadeh, Mehdi
    Foroumadi, Alireza
    Shafiee, Abbas
    EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, 2012, 50 : 113 - 123
  • [25] Blue luminescent zinc(II) complexes of 2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine and 2,6-bis[1-(2,6-dimethylphenylimino)ethyl]pyridine
    Fan, RQ
    Zhu, DS
    Ding, H
    Mu, Y
    Su, Q
    Xia, H
    SYNTHETIC METALS, 2005, 149 (2-3) : 135 - 141
  • [26] 2,6-BIS[(4-METHYL-1-PIPERAZINYL)METHYL]-4-NITROPHENOL
    VELMURUGAN, D
    GOVINDASAMY, L
    SUBRAMANIAN, E
    RAJENDRAN, TM
    KANDASWAMY, M
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1994, 50 : 931 - 933
  • [27] {2,6-bis[(diphenylphosphino)methyl]-phenyl}chloroplatinum(II)
    Fischer, S
    Wendt, OF
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2004, 60 : M69 - M70
  • [28] Structure and reaction of 2,6-bis(alkoxycarbonyl)-1-methyl-2H- and 4H-selenopyranium tetrafluoroborates
    Honda, E
    Iwamura, T
    Watanabe, S
    Kataoka, T
    HETEROCYCLES, 2000, 53 (09) : 1997 - 2008
  • [29] STRUCTURE OF (2,6-BIS[(DIMETHYLAMINO)METHYL]PHENYL)IODOPLATINUM(II)
    SMEETS, WJJ
    SPEK, AL
    DUISENBERG, AJM
    VANBEEK, JAM
    VANKOTEN, G
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1987, 43 : 463 - 465
  • [30] Structure of [2,6-bis(dimethylamino)methyl]phenyltin tribromide hydrate
    Jambor, R
    Ruzicka, A
    Brus, J
    Císarová, I
    Holecek, J
    INORGANIC CHEMISTRY COMMUNICATIONS, 2001, 4 (05) : 257 - 260