Reaction of methyl 1-bromocycloalkanecarboxylates with zinc and 2,6-bis(arylmethylene)cyclohexanones

被引:0
|
作者
N. F. Kirillov
A. G. Gavrilov
A. N. Vasyanin
S. N. Shurov
M. I. Vakhrin
P. A. Slepukhin
机构
[1] Perm State University,I.Ya. Postovsky Institute of Organic Synthesis
[2] Ural Branch of the Russian Academy of Sciences,undefined
来源
关键词
General Chemistry; Cyclohexanone; Cyclopentan; Tetrahydro; Benzylidene;
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学科分类号
摘要
Methyl 1-bromocyclopentane-, 1-bromocyclohexane-, and 1-bromocycloheptanecarboxylates react with zinc and 2,6-bis(arylmethylene)cyclohexanones to afford 4-aryl-8-(arylmethylene)-5,6,7,8-tetrahydrospiro[chromene-3,1′-cyclopentan]-2(4H)-ones, 4-aryl-8-(arylmethylene)-5,6,7,8-tetrahydrospiro[chromene-3,1′-cyclohexan]-2(4H)-ones, and 4-aryl-8-(arylmethylene)-5,6,7,8-tetrahydrospiro[chromene-3,1′-cycloheptan]-2(4H)-ones, respectively.
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页码:289 / 293
页数:4
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