Steam reforming of dimethyl ether using a membrane-catalytic reactor

被引:0
作者
A. S. Fedotov
D. O. Antonov
V. I. Uvarov
M. V. Tsodikov
S. N. Khadzhiev
机构
[1] Russian Academy of Sciences,Topchiev Institute of Petrochemical Synthesis
[2] Russian Academy of Sciences,Institute of Structural Macrokinetics and Materials Science Problems
来源
Petroleum Chemistry | 2018年 / 58卷
关键词
steam reforming; dimethyl ether; hydrogen; synthesis gas; membrane-catalytic reactor; palladium-containing membranes; porous converter; self-propagating high-temperature synthesis; heterogeneous catalysis;
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学科分类号
摘要
It has been found that during the steam reforming of dimethyl ether into synthesis gas using a porous ceramic Ni–Co-containing membrane catalytic converter, an increased hydrogen yield with H2/CO = 15–20 is reached at T = 450–500°C. Reforming in a hybrid membrane reactor with a Pd–Ru alloy membrane integrated into the reaction volume provides recovery of ultrapure hydrogen up to 50% at a temperature of 500–700°C.
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页码:62 / 67
页数:5
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