Alkylation of carboxylic acid derivatives with dialkoxytitanacyclopropane reagents

被引：0
作者：
O. G. Kulinkovich
机构：
[1] Belarussian State University,
来源：
Russian Chemical Bulletin | 2004年 / 53卷
关键词：
titanium alkoxides; Grignard reagents; titanacyclopropanes; carboxylic acid derivatives; alkylation; cyclopropanols; cyclopropylamines;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Methods for the generation of dialkoxytitanacyclopropanes (dialkoxytitanium olefin complexes) are surveyed. Alkylation of carboxylic acid derivatives with these reagents giving rise to β-titanio ketones and related species, which are spontaneously transformed into the corresponding cyclopropane compounds or react with external electrophiles, are considered.
引用
收藏
页码：1065 / 1086
页数：21
相关论文
共 50 条
  • [1] Alkylation of carboxylic acid derivatives with dialkoxytitanacyclopropane reagents
    Kulinkovich, OG
    RUSSIAN CHEMICAL BULLETIN, 2004, 53 (05) : 1065 - 1086
  • [2] Synthetic applications of intermolecular cyclopropanation of carboxylic esters with dialkoxytitanacyclopropane reagents
    Kulinkovich, O
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2004, 2004 (22) : 4517 - 4529
  • [3] Nickel(Ⅱ)-catalyzed asymmetric alkylation of acyclic oxocarbenium ions with carboxylic acid derivatives
    Pengbo Ye
    Xuan Liu
    Gang Wang
    Lei Liu
    Chinese Chemical Letters, 2021, 32 (03) : 1237 - 1240
  • [4] Nickel(II)-catalyzed asymmetric alkylation of acyclic oxocarbenium ions with carboxylic acid derivatives
    Ye, Pengbo
    Liu, Xuan
    Wang, Gang
    Liu, Lei
    CHINESE CHEMICAL LETTERS, 2021, 32 (03) : 1237 - 1240
  • [5] Polymer-supported triazenes as smart reagents for the alkylation of carboxylic acids
    Erb, B
    Kucma, JP
    Mourey, S
    Struber, F
    CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (11) : 2582 - 2588
  • [6] Enantioselective Synthesis of Acyclic α-Quaternary Carboxylic Acid Derivatives through Iridium-Catalyzed Allylic Alkylation
    Shockley, Samantha E.
    Hethcox, J. Caleb
    Stoltz, Brian M.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (38) : 11545 - 11548
  • [7] Alkylation of zwitterionic thiooxalic acid derivatives
    Martens, K
    Scheunemann, A
    Drexler, K
    Dehne, H
    Reinke, H
    Michalik, M
    MOLECULES, 2001, 6 (06) : 540 - 550
  • [8] Carboxylic Acid Derivatives in Herbicide Development
    Cai, Hui
    Gan, Xiuhai
    Jin, Zhichao
    Hao, Gefei
    JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2023, 71 (26) : 9973 - 9993
  • [9] Palladium-Catalyzed α-Arylation of Carboxylic Acid Derivatives with Grignard Reagent
    Tanaka, Daiki
    Tanaka, Shota
    Mori, Atsunori
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2014, 2014 (20) : 4254 - 4257
  • [10] Tetrahedral intermediates in reactions of carboxylic acid derivatives with nucleophiles
    Adler, M
    Adler, S
    Boche, G
    JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 2005, 18 (03) : 193 - 209
12345