Correlation of Kinetic and Thermodynamic Quantities of Tl(I)/Tl(Hg) Electroreduction with Parameters of Binary Mixtures of Water with Acetone, Acetonitrile, Methanol, and N,N-dimethylformamide

被引：0
作者：
A. G. Anastopoulos
Th. Latsinoglou
机构：
[1] Aristotle University of Thessaloniki,Laboratory of Physical Chemistry, Department of Chemistry
来源：
Journal of Solution Chemistry | 2005年 / 34卷
关键词：
Thallium electroreduction; binary mixtures; kinetic; thermodynamic parameters; solvatochromic parameters;
D O I：
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学科分类号：
摘要：
The diffusion coefficient of Tl+ ions, the standard potential, the size factor of the activated complex, and the standard rate constant of the overall reaction Tl(I)/Tl(Hg) in aqueous mixtures of acetone, methanol, acetonitrile, and dimethylformamide are related to parameters representing the composition, polarity, electron pair, and hydrogen-bond donor ability of these mixtures. The dependencies on mixture composition, and the linear and multilinear correlation with solvatochromic parameters are interpreted by assuming a heterosolvation effect in combination with a two-step ion transfer – ion adsorption mechanism.
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页码：1341 / 1356
页数：15
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