Synthesis, Characterisation and Catalytic Studies of Iron(III), Cobalt(II), Nickel(II) and Copper(II) Complexes Containing N,O Donor Ligands and Triphenylphosphine

被引：0
|
作者：
Vettaikaranpudur G. Gnanasoundari
Karuppannan Natarajan
机构：
[1] Bharathiar University,Department of Chemistry
来源：
Transition Metal Chemistry | 2004年 / 29卷
关键词：
Copper; Nickel; Cobalt; Catalysis; Catalytic Activity;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A series of new Schiff base complexes of FeIII, CoII, NiII and CuII containing Ph3P has been prepared and characterised. The Schiff bases have been prepared by the condensation of salicylaldehyde and naphthaldehyde with the appropriate aniline. The complexes have been characterised by analytical, spectral (i.r., electronic, magnetic, e.p.r., 1H-n.m.r.) and electrochemical studies. The new complexes have been used as catalysts for aromatic coupling reactions. Higher catalytic activity has been observed for NiII compared to the other complexes.
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页码：511 / 515
页数：4
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