Gas-Phase Reaction of Anisole and Phenol with Tetrachlorogermane in the Presence of Hexachlorodisilane

被引：0
作者：
E. A. Chernyshev
V. G. Bykovchenko
N. G. Komalenko
G. N. Yakovleva
M. M. Simakina
机构：
[1] State Research Institute of Chemistry and Technology of Organoelement Compounds State Research Center,
来源：
Russian Journal of General Chemistry | 2005年 / 75卷
关键词：
Phenol; Silane; Chloro; Reaction Zone; Phenoxy;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Gas-phase reaction of anisole with tetrachlorogermane in the presence of hexachlorodisilane was studied. The major reaction products are chloro(phenoxy)silane, trichloro(phenoxy)germane, 1,1,3,3-tetrachloro-1,3-disila-2-oxaindane, and 1,1,3,3-tetrachloro-1,3-digerma-2-oxaindane. The same products are formed with phenol instead of anisole. A mechanism of the reactions of anisole with GeCl4 and Si2Cl6 is proposed, that takes account of the formation in the reaction zone of dichlorosilylenes and dichlorogermylenes.
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页码：567 / 570
页数：3
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Bashkirova S.A.(undefined)undefined undefined undefined undefined-undefined
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