New method of synthesis 1-halogermatranes, germatranyl esters of H-O acids, and their stereoelectronic structure

被引：0
作者：
M. G. Voronkov
T. A. Kochina
D. V. Vrazhnov
G. S. Samokhin
A. I. Albanov
T. N. Aksamentova
L. V. Klyba
N. N. Chipanina
机构：
[1] Russian Academy of Sciences,Favorskii Irkutsk Institute of Chemistry, Siberian Branch
[2] Russian Academy of Sciences,Grebenshchikov Institute of Silicate Chemistry
来源：
Russian Journal of General Chemistry | 2008年 / 78卷
关键词：
General Chemistry; Quantum Chemical Calculation; Ammonium Salt; Germanium Atom; Germanium Dioxide;
D O I：
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中图分类号：
学科分类号：
摘要：
A fundamentally new method for the synthesis of 1-halogermatranes and germatranyl esters of oxygen-containing acids has been developed. Using this method germatranes XGe(OCH2CH2)3N (X = Hal, ClO4)were synthesized, their elemental analysis was determined, and their stereoelectronic structure was studied by the methods of multinuclear NMR, mass spectrometry, and IR spectroscopy. The obtained data correlate with the results of quantum chemical calculations.
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页码：2339 / 2343
页数：4
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